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In organic chemistry, a dipolar compound or simply dipole is an electrically neutral molecule carrying a positive and a negative charge in at least one canonical description. In most dipolar compounds the charges are delocalized. Unlike salts, dipolar compounds have charges on separate atoms, not on positive and negative ions that make up the compound. Dipolar compounds exhibit a dipole moment. Dipolar compounds can be represented by a resonance structure. Contributing structures containing charged atoms are denoted as zwitterions. 〔Braida et al.: (''A clear correlation between the diradical character of 1,3-dipoles and their reactivity toward ethylene or acetylene.'' ); J. Am. Chem. Soc.; 2010 Jun 9;132(22):7631-7〕 〔Hartmann and Heuschmann: (''Isolation of a Zwitterion in a Diels–Alder Reaction with Inverse Electron Demand'' ); Angewandte Chemie; september 1989; Volume 28, Issue 9, pages 1267–1268 〕 〔IUPAC: (Preferred IUPAC Names ); Chapter 7, September 2004, pp. 56-70〕 〔Rolf Huisgen (IUPAC): (''Cycloaddition mechanism and the solvent dependence of rate'' ); Pure & Appl. Chem.; 1980, Vol.52, pp.2283—2302.〕 Some dipolar compounds can have an uncharged canonical form. ==Types of dipolar compounds== *1,2-dipolar compounds have the opposite charges on adjacent atoms. *1,3-dipolar compounds have the charges separated over three atoms.〔 They are reactants in 1,3-Dipolar cycloadditions. *Also 1,4-dipolars,〔 1,5-dipolars, etcetera exist. 抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「dipolar compound」の詳細全文を読む スポンサード リンク
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